Preheat oven to 325°F (170°C). Line bottom of 2 (8-inch) round cake pans with parchment paper.
In a large bowl, whisk together ¼ cup (60 grams) boiling water and cocoa. Whisk in ½ cup (100 grams) sugar until dissolved. Let cool slightly, about 3 minutes. Whisk in melted chocolate, egg yolks, oil, and vanilla until well combined.
In a medium bowl, sift together flour, salt, baking powder, and baking soda. Gradually whisk flour mixture into chocolate mixture. (Mixture will be thick.)
In the bowl of a stand mixer fitted with the whisk attachment, beat egg whites at medium-high speed until foamy. Reduce mixer speed to medium-low, and add remaining ⅓ cup (67 grams) sugar in a slow, steady stream. Increase mixer speed to medium-high, and beat until medium-soft peaks form.
Fold one-third of egg white mixture into chocolate mixture. (This will thin out the batter.) Carefully fold in remaining egg white mixture in two additions. Divide batter between prepared pans (about 402 grams each). Run a knife through batter to help release any large air bubbles.
Bake until fragrant and top is firm to the touch when gently pressed, about 25 minutes. Let cool in pans on wire racks for 10 minutes. Run a small offset spatula or thin knife between cake layers and sides of pans. Remove from pans, and let cool completely on wire racks.
Place 1 cooled cake layer, upside down, on a cake plate. Brush half of Black Cherry Kirschwasser Simple Syrup (about ½ cup or 78 grams) onto cake layer.
Place 1½ cups (210 grams) Whipped Frosting in a pastry bag, and cut a 1-inch opening in tip. Pipe a thick border around edge of cake layer. Spoon Cherry Filling into center of cake layer, and gently spread until flat and reaches frosting border. Place remaining cake layer, upside down, on top. Brush remaining Black Cherry Kirschwasser Simple Syrup onto cake layer. Using frosting in pastry bag, fill any holes between cake layers, if needed; scrape any remaining frosting in bag back into bowl. Spread a thin coat of frosting on top and sides of cake to create a crumb coat. Freeze cake for 20 minutes, and refrigerate frosting.
Spread remaining Whipped Frosting on top and sides of cake as desired. Cover and refrigerate for at least 4 hours before serving. Just before serving, add Chocolate Curls to top of cake with tweezers or by sliding a wooden pick into center of curl to lift. Cover and refrigerate for up to 3 days.